Ron Perelman & Ellen Barkin – $20 Million
Meet America’s 36th richest man, Ron Perelman! In 1999, Perelman met his fourth wife, the actress Ellen Barkin, at a Vanity Fair Oscar after-party. Less than a year later and the got hitched. For five years, they were husband and wife, although many claim it was not an easy marriage whatsoever. Furthermore sources say her divorce settlement was between $20 million to $65 million.

Ron Perelman and Ellen Barkin – 20 Million