Here Are The Celebrities Who Married Their Third Party

Angelina Jolie

This was a real heartbreaker! Their chemistry blossomed during the production of Mr. & Mrs. Smith in 2004. Brad was still married to Jennifer Aniston at the time. Pitt and Aniston divorced in 2005, and “Brangelina” was born a year later, with a kid on board. In 2016, Brad and Angelina will call it quits on their relationship.

Angelina Jolie